Radioactivity of Shale Drill Cuttings
July 4, 2013
Gas Drilling Awareness for Cortland County
January 10, 2012 2 Comments
Marcellus_Radon (application/pdf Object).
Radon in Natural Gas from Marcellus Shale
By Marvin Resnikoff, Radioactive Waste Management Associates
Executive Summary*
January 10, 2012
A significant public health hazard associated with drilling for natural gas in the Marcellus
Shale formation must be seriously investigated by the New York State Department of
Environmental Conservation (DEC). This hazard is from radioactive radon gas and the
potential for large numbers of lung cancer among natural gas customers. This issue,
which has been ignored in the DEC’s Draft Supplemental Environmental Impact
Statement, must be addressed in a revised Impact Statement and before DEC issues any
drilling permits.
Unlike present sources for natural gas, located in Texas and Louisiana, the Marcellus
Shale is considerably closer to New York consumers. In addition, the radioactive levels
at the wellheads in New York are higher than the national average for natural gas wells
throughout the US.
In this paper Radioactive Waste Management Associates calculates the wellhead
concentrations of radon in natural gas from Marcellus Shale, the time to transit to
consumers, particularly New York City residents, and the potential health effects of
releasing radon, especially in the smaller living quarters found in urban areas.
It is well known that radon (radon-222) is present in natural gas.1 Published reports by R
H Johnson of the US Environmental Protection Agency2 and C V Gogolak of the US
Department of Energy3 also address this issue. Radon is present in natural gas from
Marcellus Shale at much higher concentrations than natural gas from wells in Louisiana
and Texas.
Since radon is a decay product of radium-226, to calculate radon levels it is necessary to
know the concentrations of radium-226, Based on a USGS study4 and gamma ray logs
(also known as GAPI logs) that we have examined, the radium concentrations in the
* Great appreciation for the excellent assistance of Minard Hamilton, RWMA Associate
1 Agency for Toxic Substances and Disease Registry, Toxicological Profile for Ionizing Radiation and
U.S. National Research Council, Health, Risks of Radon and Other Internally Deposited Alpha-Emitters:
BEIR IV (National Academy Press, 1988)
2 Johnson,R.H. et al, “Assessment of Potential Radiological Health Effects from Radon in Natural Gas,”
Environmental Protection Agency, EPA-520-73-004, November 1973.
3 Gogolak, C.V., “Review of 222 Rn in Natural Gas Produced from Unconventional Sources,” Department
of Energy, DOE/EML-385, November 1980
4
J.S. Leventhal, J.G. Crock, and M.J. Malcolm, Geochemistry of trace elements in Devonian shales of the
Appalachian Basin, U.S. Geological Survey Open File Report 81-778, 1981
Radon in Natural from Marcellus Shale Page 2
Marvin Resnikoff, Ph.D. RWMA
Marcellus Shale is 8 to 32 times background. This compares to an average radium-226 in
surface soil in New York State of 0.81 picoCuries per gram (pCi/g)5
Using this range of radium concentrations and a simple Fortran program that simulates
the production of radon in the well bore, and transit to the wellhead, we calculate a range
of radon concentrations at the wellhead between 36.9 picoCuries per liter (pCi/L) to 2576
pCi/L.
These wellhead concentrations in Marcellus shale are up to 70 times the average in
natural gas wells throughout the U.S. The average was calculated by R.H.Johnson of the
US Environmental Protection Agency in 1973 (pre-fracking) to be 37 pCi/L6 to a
maximum of 1450 pCi/L.
In addition, the distance to New York State apartments and homes from the Marcellus
formation is 400 miles and sometimes less. This contrasts with the distance from the
Gulf Coast and other formations which is 1800 miles. At 10 mph movement in the
pipeline, natural gas containing the radioactive gas, radon, which has a half-life of 3.8
days, will have three times the radon concentrations than natural gas originating at the
Gulf Coast., everything else being equal, which it is not..
Being an inert gas, radon will not be destroyed when natural gas is burned in a kitchen
stove.
We have examined published dilution factors and factored in numbers for average urban
apartments where the dilution factor and the number of air exchanges per hour are less
than those of non-urban dwellings. This analysis implies that the radon concentrations in
New York City and urban apartments is greater than the national average.
We assume a figure of 11.9 million residents affected. This figure is calculated in the
following manner: Based on US Department of Energy figures our calculations assume
4.4 million gas stoves in New York State. This figure is multiplied by 2.69 persons per
household to determine the number of residents affected: this number equals 11.9 million.
We calculate the number of excess lung cancer deaths for New York State. Our results:
the potential number of fatal lung cancer deaths due to radon in natural gas from the
Marcellus shale range from 1,182 to 30,448.
This is an additional number of lung cancer deaths due to radon from Marcellus Shale
over deaths from natural radon already impacting New York State homes and their
residents.
5 Myrick, T. E., et al. 1981. State Background Radiation Levels: Results of Measurements Taken During
1975-1979, ORNL/TM-7343, Oak Ridge, Tenn..
6 Johnson, Op cit.
The Draft Supplemental Environmental Impact Statement produced by the New York
State Department of Environmental Conservation needs to be revised to take into account
this public health and environmental hazard. In the entire 1400 page statement there is
only one sentence containing the word “radon” and no consideration of this significant
public health hazard.
Further, NYDEC needs to independently calculate and measure radon at the wellhead
from the Marcellus Shale formation in presently operating wells before issuing drilling
permits in New York State. The present RDSGEIS should be withdrawn.
November 18, 2011 1 Comment
Dr. Marvin Resnikoff – Radioactivity in the Marcellus Shale on Vimeo on Vimeo
via Dr. Marvin Resnikoff – Radioactivity in the Marcellus Shale on Vimeo.
One fascinating (and frightening) tidbit from his presentation was that radon gas comes into people’s homes along with natural gas when they use it for heating or cooking. Watch the video to see Dr. Resnikoff’s staggering estimate of the number of additional deaths from lung cancer that are statistically attributable to this influx of radon gas.
October 19, 2011
Radiation Problems due to Hydrofracking | Shaleshock Media.
In this interview with Dr. Marvin Resnikoff, the threats of radiation problems due to hydrofracking in the Marcellus Shale are discussed. For more information about Dr. Resnikoff, go to http://rwma.com/
For more information about the problems with hydrofracking in the Marcellus Shale, go to http://newyorkwater.org/
May 19, 2011
New York State Dismisses Radiation Threat From Gas Drilling Cuttings.
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Drill cuttings. Photo: drillingcontractor.org
As they prepare final rules for high-volume hydrofracking of natural gas wells in New York, state environmental regulators are brushing aside warnings from scientists and public health organizations that radioactive drill cuttings from Marcellus Shale wells pose serious environmental risks.
The New York State Department of Environmental Conservation already allows three western New York landfills operated by Casella Waste Systems to import Marcellus well cuttings from Pennsylvania. And a landfill owned and operated by Steuben County is poised to become New York’s fourth cuttings importer, also with the DEC’s blessing.
“This stuff is so innocuous that under law and regulation and good environmental practice, it could be [buried] at the drill site,” Scott Foti, a DEC official, testified in January. “It could be left right there.”
The DEC expects an exponential increase in drill cuttings after the agency begins granting permits for high-volume hydrofracking of horizontal Marcellus Shale wells in New York, possibly as soon as this fall. Foti said the agency is weighing whether to allow drillers the option of disposing of cuttings at municipal landfills or at well sites.
Both those options alarms scientists, public health officials and environmental activists, who note that the Marcellus tends to be rich in naturally occurring radioactive material, or NORM.
Conrad Volz. Photo: Protectingourwaters.wordpress.com
“That’s not appropriate,” said Conrad Volz, an assistant professor at the University of Pittsburgh’s Graduate School of Public Health. “I don’t have a problem with cuttings from lots of other shale formations, but the Marcellus is unique. It’s highly enriched in radium isotopes and thorium. Cuttings from horizontal wells in the Marcellus should be taken to low-level radiological waste disposal sites.”
Volz noted that radiation levels in the Marcellus formation may vary widely from region to region and even from well to well within neighborhoods. For that reason alone, he said, each batch of cuttings should be tested before choosing a disposal option.
That is the stance the New York State Conference of Environmental Health Directors took in a December 2009 letter to the DEC, which said:
“The idea that NORM is not a problem with drill cuttings is based on two samples. This is clearly not sufficient. Since the major disposal option is burial at local landfills, NORM sampling should be done for each batch of drill cuttings prior to transport and disposal, at least until a large-scale sampling program establishes the safety of such materials.”
Instead of following that advice, the DEC has chosen to generalize based on a handful of samples, most of which were gathered and analyzed by a contractor hired by Casella, the disposal company.
The agency has acknowledged conducting its own tests on rock samples from two vertical Marcellus wells drilled in Western New York. Gamma ray spectrography analysis of rocks from those two wells revealed “essentially background values” for NORM, according to the DEC’s 2009 draft of rules for high-volume hydrofracking.
The agency plans to release a new version of the drilling rules this summer or fall. After it holds public hearings and makes the rules final, it plans to begin issuing horizontal Marcellus well permits promptly.
In order to clarify whether the agency has conducted other tests beyond the two wells mentioned in its 2009 draft of drilling rules, DCBureau.org asked the agency to specify the exact total number of Marcellus wells it had tested.
Agency officials took three weeks to respond and then declined to provide a specific number. Instead, they wrote in an email that the agency was “satisfied with the breadth and objectivity of the sampling” and believed that disposal of Marcellus cuttings in municipal landfills “does not pose an environmental concern.”
The DEC’s conclusion, the email said, “is based on analysis performed on Marcellus Shale rock samples from the New York State Museum collection and from the known properties of shale formations.” The email went on to cite a “comprehensive study” conducted for Casella by CoPhysics Corp., which “further supported the DEC position” that Marcellus cuttings are harmless.
The CoPhysics report has been sharply criticized by Volz and other scientists for weaknesses in its methodology, it relatively small sample size and its failure to report test results for alpha and beta emissions as well as gamma emissions.
Both the DEC and CoPhysics tests relied on measurements of gamma ray emissions. Volz called the decision to test exclusively for gamma rays “ridiculous” in light of the fact that the main threat in Marcellus cuttings is radium, an alpha-particle emitter. Alpha particles make up 96 percent of the radiation emitted by radium, while gamma rays make up only 4 percent.
“To look for radium, you have to test for alpha,” said Marvin Resnikov, senior associate at Radioactive Waste Management Associates in New York City. “CoPhysics tested for gamma, not alpha.”
Stephen Penningroth, executive director of the Community Science Institute in Ithaca, N.Y., a state-licensed water tester, agreed with Volz and Resnikov. “The low gamma readings may be correct,” Penningroth said. “But the other part of the problem is alpha and beta, and that’s where the NORM is.”
While Geiger counters detect gamma rays effectively, they’re not much use picking up alpha particle emissions, which travel only a few centimeters and may be blocked by thin clothing or even layers of dead skin.
But alpha-emitting materials are very dangerous when they are ingested as liquids or breathed in with dust in the air.
“When alpha-emitters get in the body, they can set up business next to cells and bombard them with nuclei,” Volz said. The main dangers from NORM-contaminated drill cuttings are dust, radon and any water that leaches away from them after they are buried.
The DEC confirmed that the Marcellus Shale in New York tends to have dangerous levels of NORM when it tested the brine from all 12 of the state’s conventional Marcellus wells in 2008 and 2009. It found levels of Radium 226, a dangerous alpha-emitter, to be far above allowable limits for drinking water (5 picocuries/liter) or for release into the environment (60 picocuries/liter). The DEC’s readings for Radium 226 in brine from four of the tested wells exceeded 10,000 picocuries/liter.
Radium 226 has a half-life of about 1,600 years and decays into radon gas, the world’s second leading cause of lung cancer. Only smoking causes more.
That’s why Dr. Earl Robinson, a pulmonologist from Elmira, and others who live near to the Chemung County landfill were upset to learn Marcellus drilling wastes from Pennsylvania were being dumped near their homes.
New England Waste Services of New York, a unit of Casella that operates the Chemung Landfill under a 25-year, $90-million contract, began accepting Marcellus wastes from Pennsylvania early last year, even before notifying the DEC.
Robinson leads a citizens group that has mounted a legal challenge to Casella’s authority to bring radioactive waste into a landfill that is not licensed to handle it. An administrative law judge at the DEC heard evidence last summer, but he is still considering the matter — seven months after an attorney for Casella filed a motion for an expedited ruling.
As the months have ticked by without a ruling, the Chemung Landfill and other Casella-operated New York State landfills in Painted Post and Angelica have continued to import Marcellus cuttings from Pennsylvania.
Several months ago, Steuben County began to consider accepting Marcellus cuttings at its municipal landfill.
Vince Spagnoletti, the county’s public works commissioner, said that he studied the environmental issues carefully and decided to recommend that county officials vote to accept between 10,000 and 15,000 tons of Pennsylvania cuttings a year– two or three dump trucks a day — beginning later this summer. That vote could come in June, he added.
That volume of cuttings would generate more than $300,000 in fees for the county, Spagnoletti said in a recent interview. And the county might eventually triple that volume, he said.
Casella has no involvement in the Steuben initiative, though Spagnoletti said he has drawn on data and advice from two contractors hired by Casella, CoPhysics and Barton & Loguidice of Syracuse.
The CoPhysics report was introduced in the Chemung Landfill case and is public record. A study by Barton & Loguidice, a follow-up to the CoPhysics report that has not been made part of the public record, is based on the samplings taken for the CoPhysics report.
CoPhysics analyzed drill cuttings taken from four Marcellus wells in Bradford and Tioga counties in Pennsylvania, cuttings transported to Casella’s Chemung, Painted Post and Angelica landfills, and “local background soil and rock” from the same three Casella landfills.
The CoPhysics report concluded that “rock cuttings from the gas drilling operations, as sampled during this project, have radionuclide levels that do not pose any environmental health problem even if they were deposited in areas accessible by the general public. Therefore, they are certainly acceptable for landfill disposal.”
At a public hearing Feb. 3, several Steuben County residents expressed skepticism about the conclusion. They also took issue with the DEC’s (and Spagnoletti’s) willingness to accept them at face value despite the fact that they were paid for by Casella, which stands to gain financially from a conclusion the cuttings are harmless.
At an public meeting in Steuben County on January 11, Foti acknowledged that questions might be raised about reliance on data from potentially biased private sources, but he dismissed the concern, saying:
“There were some people who were concerned about this technique of a company who has an interest in the outcome being involved in paying for the samples,” Foti testified. “We’ll, I’ve got to tell you, it’s very, very routine. …I do trust the data.”
Foti also wrote a Feb. 14 letter to Spagnoletti that said the DEC had determined that disposal of Marcellus drill cuttings in non-hazardous-waste landfills “is consistent with regulatory requirements and the protection of the environment.”
That finding was based on the DEC’s conclusion that for purposes of regulation, Marcellus drill cuttings were neither “hazardous waste” nor “industrial waste” nor “radioactive waste,” Foti explained.
Cuttings are neither hazardous nor industrial waste because statutes exempt wastes from natural gas development from those categories, no matter how contaminated. Neither can the drill cuttings be regulated as “radioactive waste,” he said, because NORM is exempt from the definition of radioactive waste unless it has been “processed and concentrated.”
The DEC confirmed in its recent email that it had concluded that the drill cuttings are never “processed and concentrated” and therefore do not fall under the regulatory definition of radioactive waste.
Three expert witnesses in the Chemung Landfill case — Volz, Resnikov and Tony Ingraffea, a Cornell University professor of rock fracture mechanics — disputed that interpretation of the regulation. But as long as the Chemung Landfill case remains stalled within the DEC, the agency’s interpretation holds.
“The DEC plays with regulations. They’re not charged with looking after public health. They’re not trying to prevent disease,” said Volz, who plans to leave the University of Pittsburgh to write a book on the environmental costs of extracting oil and natural gas worldwide.
The DEC’s interpretation that Marcellus drill cuttings cannot be regulated as radioactive waste because they are not “processed and concentrated” raises questions about the agency’s authority to regulate Marcellus brine, a confirmed health risk that is no more “processed and concentrated” than the cuttings.
In fact, the DEC has downplayed the results of its own tests of Marcellus brine, even as other agencies have expressed alarm about them.
For example, the New York City Department of Environmental Protection said the data “raise serious issues for public health.” The city’s top environmental officer, Steven W. Lawitts, wrote the DEC in 2009, saying the agency was obliged to do further testing. “Such an analysis must be completed before any activity that is likely to generate radioactive waste can move forward.” The DEC rejected that advice, saying it would wait and see the results of actual drilling in the New York Marcellus.
The regulatory loopholes that restrain the DEC from taking a more rigorous look at waste from Marcellus gas wells have drawn the attention of two members of the New York General Assembly.
Assemblyman Alan Maisel (D-Brooklyn) has introduced a bill that would place a moratorium on the importation from other states of all Marcellus wastes, both liquid and solid, until the U.S. Environmental Protection Agency reports on the public health effects of high-volume hydrofracking. There is no companion bill in the state Senate.
Meanwhile, Assemblyman Robert Sweeney (D-Lindenhurst), the chair of the Assembly’s Environmental Conservation Committee, is sponsoring a bill that would remove the oil and natural gas industries’ special exemption from the regulation as hazardous waste. A similar bill has been introduced in the state Senate.
“There is no compelling reason why waste produced from oil and natural gas activities that meets the definition of hazardous waste, should not be subject to the same laws regarding generation, transportation, treatment, storage and disposal as other hazardous wastes,” Sweeney said in a memo explaining the bill’s purpose.
DEC officials declined to comment on the Maisel and Sweeney bills, saying the agency does not take a position on pending legislation. Yet the DEC drafts and actively sponsors bills that it favors, such as this year’s proposed overhaul of the state’s water withdrawal rules.
Although the controversy over Marcellus drill cuttings has focused on NORM, some environmental advocates raise concerns about other potentially hazardous substances that may be headed to the landfills with the solid waste.
In his testimony before Steuben legislators Jan. 11, Foti described cuttings as dry rock chips that were less radioactive than the marble counters in his kitchen at home.
But in his Feb. 14 letter to Spagnoletti, he acknowledged that ground-up rock cuttings emerge from natural gas wells in a slurry of rocks and drilling mud, which is added to facilitate drilling and the removal of cuttings. That mixture is saturated with naturally-occurring brine.
A microscopic view of Drill cuttings of shale and sand. Photo: Wikicommons / Mudgineer
A dewatering process removes most of the liquids, and the remaining rocky residue is then bulked up with sawdust in preparation for disposal.
But municipal landfills are permitted to accept the cuttings even if they contain up to 20 percent liquids.
Kate Bartholomew, the chair of the Schuyler County Environmental Management Council in Watkins Glen, N.Y., said she was concerned about the residual drilling mud and brine disposed of with the cuttings.
In horizontal wells such as those used to tap the Marcellus Shale, drillers use an oil-based mud that includes potentially dangerous chemicals, she noted. While some batches of the rock-liquid mix may be innocuous, she said, others may be so contaminated that they belong in landfills specially licensed to handle hazardous waste or radioactive waste.