Geochemical evidence for possible natural migration of Marcellus Formation brine to shallow aquifers in Pennsylvania
July 10, 2012
1121181109.full.pdf (application/pdf Object).
Geochemical evidence for possible natural migration of Marcellus Formation brine to shallow aquifers in Pennsylvania
The debate surrounding the safety of shale gas development in the
Appalachian Basin has generated increased awareness of drinking
water quality in rural communities. Concerns include the potential
for migration of stray gas, metal-rich formation brines, and hydraulic
fracturing and/or flowback fluids to drinking water aquifers.
A critical question common to these environmental risks is the
hydraulic connectivity between the shale gas formations and the
overlying shallow drinking water aquifers. We present geochemical
evidence from northeastern Pennsylvania showing that pathways,
unrelated to recent drilling activities, exist in some locations
between deep underlying formations and shallow drinking water
aquifers. Integration of chemical data (Br, Cl, Na, Ba, Sr, and Li) and
isotopic ratios (87Sr∕86Sr, 2H∕H, 18O∕16O, and 228Ra∕226Ra) from
this and previous studies in 426 shallow groundwater samples and
83 northern Appalachian brine samples suggest that mixing relationships
between shallow ground water and a deep formation
brine causes groundwater salinization in some locations. The
strong geochemical fingerprint in the salinized (Cl > 20 mg∕L)
groundwater sampled from the Alluvium, Catskill, and Lock Haven
aquifers suggests possible migration of Marcellus brine through
naturally occurring pathways. The occurrences of saline water do
not correlate with the location of shale-gas wells and are consistent
with reported data before rapid shale-gas development in the region;
however, the presence of these fluids suggests conductive
pathways and specific geostructural and/or hydrodynamic regimes
in northeastern Pennsylvania that are at increased risk for contamination
of shallow drinking water resources, particularly by fugitive
gases, because of natural hydraulic connections to deeper
COMMENTS
“New research on Marcellus Shale gas drilling in Pennsylvania may only add fuel to the debate over whether the industry poses long-term threats to drinking water.
A paper published on Monday by Duke University researchers found that gas drilling in northeastern Pennsylvania did not contaminate nearby drinking water wells with salty water, which is a byproduct of the drilling.
“These results reinforce our earlier work showing no evidence of brine contamination from shale gas exploration,………”
“Hydraulic fracturing for natural gas in Pennsylvania may contaminate drinking-water supplies, a study by Duke University professors concluded……..”
http://www.pnas.org/content/early/2012/07/03/1121181109.full.pdf
Rising Shale Water Complicates Fracking Debate

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Yup;
Gives a window into how confused many citizens (and politicians) must be at this point (in time).
Also shows, I believe the ENORMOUS influence of the industry on the media – sorta like: no evidence that smoking causes cancer but probably even higher stakes.